ZHONGDECustomizing | Manufacturing
Oct 20-2020 Views: 2012
The so-called mold forming is the process of filling the rubber compound into the cavity of a metal mold and vulcanizing it into a silicone product. However, due to the residual air and vulcanization gas in the cavity, the structure of the mold must be able to eliminate the residual gas through the pressure formed by the flow of rubber. The rubber must flow and contact the mold that has been heated to the curing temperature. Therefore, the rubber must maintain proper fluidity. The side of the cavity should not hinder the flow of the rubber material, and the product after vulcanization should have good mold release.
In the compression molding process, the structure of the mold and the fluidity of the rubber material are the top priorities in the molding process. Compression molding must first consider the function of the product. Molding methods for silicone products include rubber injection molding and rubber compression molding. This article focuses on the compression molding of the widely used combined molds and explains the quality problems and solutions of the compression molding process.
The so-called surface state is the processing state of the mold surface, and the poor surface state is mostly caused by the scorching of the rubber compound. The scorch of the rubber compound is also affected by the change of parking conditions and time. It is often caused when the rubber compound flows in a high-temperature mold. At this time, the surface roughness in a wrinkled state can be seen. In addition, different smooth circular bright spots are also produced on the surface of the product. It can be considered that this is due to the release agent, which often occurs in the use of compounding agents that generate more gas and highly filled rubber compounds. The release agent should be evenly coated, and the molded product after vulcanization should be quickly released from the mold.
Collapse occurs on the surface of the molded product. This is because the mold is not exhausted and the amount of rubber filling is insufficient. Exhaust uses the elasticity of the rubber and the expansion force of the gas, so it loses the low viscosity effect that can make the rubber adhere to the surface of the model. On the other hand, the filling amount of the rubber in the cavity is insufficient, so that the fluidity of the rubber is not fully utilized, resulting in the loss of the rubber to the outside of the cavity. As a countermeasure to solve this problem, the application of the release agent should be uniform and the speed of pressing the rubber should be slowed down.
The reason for the fine collapse is considered to be due to poor dispersion of the melt compounding agent at the vulcanization temperature. The rubber material should be filtered or thinned to remove poorly dispersed additives. At this time, it should also be noted that the viscosity of the rubber compound will decrease and the vulcanization characteristics will also change. In addition, the generation of tiny pores is caused by the mixing of dissimilar materials and foreign substances into the rubber compound during the mixing operation. Others, such as the moisture absorption of the filler or the excessive cooling of the processing machinery during the mixing operation, will cause the product to have pores after vulcanization. In this case, the mold is easily contaminated, and the scorch of the rubber compound is promoted due to the matching, which affects the electric insulation and thermal aging of the rubber compound. Therefore, the rubber compound cannot be used. The remaining bubbles in the rubber are often formed by air mixing during the calendering, and they can be eliminated by promoting the flow or exhaust of the rubber in the model; on the contrary, when the rubber fluidity is weak, it will produce defects such as flow marks. , If this is the case, large bubbles can be punctured.
Flow marks are traces of rubber flow left on the surface of the product, in different states such as line and crack. The reason is that there is a problem with the flow of the rubber. The different viscosity caused by the difference in the heating state, the partial scorching of the rubber, and the contamination of the model surface will all cause obstacles to the rubber flow. During the compression molding process, the rubber material enters the mold, contacts the surface of the mold and is heated, and a temperature gradient is generated on the surface and the inside of the rubber material, which causes the rubber material to flow unevenly in the cavity. The measures to be taken are to preheat the rubber material before entering the mold, or keep the rubber material in a low-pressure flow state during molding, and exhaust in a short period of time. At the same time, the molding pressure must always remain the same. For other reasons, there are substances deposited on the surface of the rubber compound, and the powder applied to prevent adhesion will affect it. The rubber is stored for a long time and is easy to cause blooming, so it is necessary to set the safe use period of the rubber after mixing. Also, excessive use of coating powder and release agent are both causes of flow marks.
Due to the pins and core plugs in the cavity, the flow of the rubber material is cut off and then resumes the flow. The traces produced at this confluence are called weld lines or weld marks. The strength of the confluence part is low, which can easily become the starting point of failure. The reason is that air, materials that lack compatibility and materials such as mold release agents accumulate here, and the surface of the product becomes blurred in the initial stage of continuous production, and then gradually dirt is generated on the mold surface. Clean the mold as soon as possible. In addition, the fast-vulcanized rubber will scorch on the flowing surface. Therefore, attention should be paid to the thermal history of the preforming process (calendering, extrusion) and the parking time of the rubber. With the increase of the parking time of the same batch of rubber, the defective rate of the rubber will gradually increase. As a way to solve this problem, the coating amount of the release agent should be small, or the sintered release agent should be used. For the residual air, while considering the flow direction of the rubber compound, attention should be paid to timely exhaust. When scorching occurs, it is necessary to shorten the thermal history during operation, and at the same time, wait for the rubber compound to cool before stacking.
The so-called mold shrinkage is irregularly shaped dents at the joints of large thick-walled products and cylindrical products, which is also called mold cracking. The inner surface of cylindrical products may also have scars. There is a difference between the vulcanization rate of the surface layer rubber and the inner rubber that contact the mold. As the internal temperature of the rubber slowly rises, the internal pressure rises due to thermal expansion, causing the vulcanization of the surface layer to be squeezed to the clamping surface, and this part of the vulcanized rubber is damaged at the corners of the mold.
If it is a cylindrical product, the same phenomenon will occur due to the low core temperature and thermal expansion caused by the temperature rise during the vulcanization process. For the above reasons, consider making the temperature of the rubber contacting the mold surface the same as the temperature of the internal rubber, or vulcanizing the rubber surface and the inside in approximately the same state, first heating the rubber, and then injecting it into the cavity , This is difficult to do in injection molding; and the solution in compression molding is not perfect, this is the status quo. One way to solve this problem is to round the burr corners of the mold and install a heat source on the core to keep it warm. During molding, the rubber material is heated to the scorch temperature, and the surface of the cavity is cooled with cold water to form a temperature gradient. This is a very effective measure.
Poor gloss means that the surface is dim and has no gloss, and the transparency of transparent products is low.
In the silicone rubber industry, the molding technology of solid silicone products is gradually mature.